Resources Science ›› 2021, Vol. 43 ›› Issue (2): 368-379.doi: 10.18402/resci.2021.02.14
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TAN Li(), WANG Zhanqi(
), XUE Zhibin, YANG Bin
Received:
2020-06-18
Revised:
2020-09-19
Online:
2021-02-25
Published:
2021-04-25
Contact:
WANG Zhanqi
E-mail:280368711@qq.com;zhqwang@cug.edu.cn
TAN Li, WANG Zhanqi, XUE Zhibin, YANG Bin. Spatial variability and pollution risk assessment of soil fluorine in the core area of the Middle Route of the South-to-North Water Transfer Project[J].Resources Science, 2021, 43(2): 368-379.
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Table 1
Statistics of land use types in the core area of the Middle Route of the South-to-North Water Transfer Project"
地类名称 | 面积/km2 | 占比/% |
---|---|---|
耕地 | 1176.81 | 19.54 |
园地 | 410.74 | 6.82 |
林地 | 2915.54 | 48.41 |
草地 | 103.59 | 1.72 |
商服用地 | 52.41 | 0.87 |
工矿仓储用地 | 128.28 | 2.13 |
住宅用地 | 171.04 | 2.84 |
公共管理与公共服务用地 | 40.95 | 0.68 |
特殊用地 | 16.86 | 0.28 |
交通运输用地 | 37.34 | 0.62 |
水域及水利设施用地 | 930.49 | 15.45 |
其他土地 | 38.54 | 0.64 |
合计 | 6022.59 | 100.00 |
Table 2
Sample testing methods"
检测项目 | 检测方法 | 主要仪器设备 | 检出限 |
---|---|---|---|
pH | NY/T 1377-2007 | 多参数水质分析仪 HQ30D | — |
全氮 | 凯氏法 HJ 717-2014 | 容量瓶 | 48.00 mg/kg |
总磷 | 碱熔-钼锑抗分光光度法 HJ 632-2011 | 可见分光光度计 722 | 10.00 mg/kg |
全氟 | 选择性离子电极法(ISE)GB/T 22104-2008 | 氟离子选择电极 | 25.00 mg/kg |
铬 | 电感耦合等离子体质谱法 HJ 766-2015 | 电感耦合等离子体发射质谱仪 NexION 350D | 1.00 mg/kg |
镍 | 电感耦合等离子体质谱法 HJ 766-2015 | 电感耦合等离子体发射质谱仪 NexION 350D | 1.90 mg/kg |
铜 | 电感耦合等离子体质谱法 HJ 766-2015 | 电感耦合等离子体发射质谱仪 NexION 350D | 1.20 mg/kg |
锌 | 电感耦合等离子体质谱法 HJ 766-2015 | 电感耦合等离子体发射质谱仪 NexION 350D | 3.20 mg/kg |
砷 | 微波消解/原子荧光法 HJ 680-2013 | 原子荧光光度计 AFS-8510 | 0.50 mg/kg |
镉 | 电感耦合等离子体质谱法 HJ 766-2015 | 电感耦合等离子体发射质谱仪 NexION 350D | 0.60 mg/kg |
铅 | 电感耦合等离子体质谱法 HJ 766-2015 | 电感耦合等离子体发射质谱仪 NexION 350D | 2.10 mg/kg |
硒 | 微波消解/原子荧光法 HJ 680-2013 | 原子荧光光度计 AFS-8510 | 0.60 mg/kg |
汞 | 微波消解/原子荧光法 HJ 680-2013 | 原子荧光光度计 AFS-8510 | 0.002 mg/kg |
Table 5
Descriptive statistics of soil fluorine content in the core area of the Middle Route of the South-to-North Water Transfer Project"
项目 | 样品数 | 氟含量/(mg/kg) | 变异系数/% | 偏度 | 峰度 | |||||
---|---|---|---|---|---|---|---|---|---|---|
最大值 | 最小值 | 中值 | 平均值 | 标准差 | ||||||
原数据 | 表层 | 7735 | 4760.80 | 133.00 | 565.80 | 593.72 | 222.66 | 37.50 | 3.978 | 37.920 |
底层 | 88 | 1166.00 | 200.30 | 570.10 | 574.79 | 175.16 | 30.47 | 0.917 | 1.505 | |
处理后 | 表层 | 7735 | 1260.00 | 133.00 | 565.80 | 586.83 | 182.20 | 31.05 | 1.325 | 2.994 |
底层 | 88 | 983.50 | 200.30 | 570.10 | 571.32 | 165.19 | 28.91 | 0.593 | 0.413 |
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